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Why are column dimensions and pore volume so important in GPC/SEC?

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Why are column dimensions and pore volume so important in GPC/SEC?

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Columns with larger total pore volume provide increased resolving power. For example a 10mm ID Jordi brand column offers 64% more pore volume than a conventional 7.8mm PS-DVB thereby giving the same resolving power as 3 columns of the same length.

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