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Why do some elements, like iron, have more than one valance number?

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Why do some elements, like iron, have more than one valance number?

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Some elements, like the transition metals, have electron configurations in which electrons from their inner shells can also be used as valence electrons; these elements can have several different oxidation states. For example, iron can have a valence of +2 or +3, and chromium can have a valence of +2, +3, or +6. Iron in the +3 oxidation state, Fe+3, acts as an oxidizing agent, accepting one electron to attain the Fe+2 state, while ferrous iron, Fe+2, by donating an electron in going to the +3 state, acts as a reducing agent.

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