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Why may concrete deteriorate from freeze thaw actions?

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Why may concrete deteriorate from freeze thaw actions?

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Deterioration of concrete from freeze thaw actions may occur when the concrete is critically saturated, which is when approximately 91% of its pores are filled with water. When water freezes to ice it occupies 9% more volume than that of water. If there is no space for this volume expansion in a porous, water containing material like concrete, freezing may cause distress in the concrete. Distress to critically saturated concrete from freezing and thawing will commence with the first freeze-thaw cycle and will continue throughout successive winter seasons resulting in repeated loss of concrete surface. To protect concrete from freeze/thaw damage, it should be air-entrained by adding a surface active agent to the concrete mixture. This creates a large number of closely spaced, small air bubbles in the hardened concrete. The air bubbles relieve the pressure build-up caused by ice formation by acting as expansion chambers. About 4% air by volume is needed and the air-bubbles should be well

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